Explosive Materials Disposal
Definition of Explosives
Explosives are a class of materials, either solids or liquids, that can undergo a rapid chemical decomposition when subject to an external force (shock, friction, sparks, etc.).
The rate of decomposition across the explosive material travels faster than the speed of sound, and produces large amount of heat and gas.
The amount of energy required to initiate this chemical reaction determines the sensitivity and stability of the explosive material.
There are several common laboratory reagents that can become unstable or explosive. Factors that can transform common reagents into explosives may be as simple as extended storage time, increased storage temperatures, or allowing a material to dry out.
What Happens if I Locate an Explosive Material?
Whenever you find or suspect that you have found a potentially explosive material,
- DO NOT MOVE THE CONTAINER.
- Post a sign, and alert personnel in your area of your discovery.
- CONTACT HEALTH & SAFETY 915-5433.
If a peroxidized compound (see list below) forms within a screw cap bottle, some of the potentially explosive material may rest within the threads inside the cap. Unscrewing the cap may initiate an explosion.
- When a material is identified as explosive, Health and Safety must take specific precautions to
- Remove the material from high traffic areas,
- Transport the material away from personnel or buildings, and,
- Stabilize, Dilute or Detonate the material.
- Additional State and Federal requirements come into play when dealing with explosive materials.
- Removal and/or disposal may take an extended period of time to complete.
- Please be patient.
- We are concerned for your safety, as well as for our own.
Common Explosive Materials
The most Common Explosive and Peroxides forming Materials found on this campus are:
- Picric Acid (2,4-Trinitro Phenol) that has become dry
- Dinitro Phenyl Hydrazine
- Diethyl Ether (Ethyl Ether)
- Isopropyl Ether
To see the Laboratory Exemption for Common Explosive Materials as defined by Alcohol, Tobacco and Firearms, please follow this LINK.
Peroxide Forming Materials Materials These common materials that can form peroxides during extended storage.
Chemicals that form explosive levels of peroxides without concentration:
Chemicals that form explosive levels of peroxides on concentration:
Acetal Acetaldehyde Benzyl alcohol 2-Butane Cumerie Cyclohexanol 2-Cyclohexen-1-ol Cyclohexene Decahydronaphtalene Diacetylene Dicyclopentadiene Diethyl ether Diethyl glycol dimethyl ether (dyglyme) Dioxanes Ethylene glycol dimethyl ether (glyme) 4 Heptanol 2-Hexanol Methyl 1 -butanol Methylcyclopentane Methyl isobutyl ketone 4-Metho1 2- pentanol 2 Pentanol 4-Pentan-1 ol 1 Phenylethanol 2 Phenylethanol 2 Propanol Tetrahydronaphthalene Vinyl ethers Other secondary alcohols
Chemicals that may autopolymerize as a result of peroxide accumulation:
Acrylic acid b Acrylonitirile b Butadiene c Chloroprene c Methyl Methacrylate b Styrene Tetrafiuoroethylene c Vinyl acetate Vinyl acetylene Vinyl chloride Vinyladiene chloride
- When stored as a liquid monomer.
- Although these chemicals form peroxides, no explosion involving these monomers have been reported.
- When stored in liquid form, these chemicals form explosive levels of peroxides without concentration. They may also be stored as a gas in gas cylinders. When stored as a gas, these chemicals may autopolymerize as a result of peroxide accumulation.
- These chemicals easily form peroxides and should probably be considered under part B.
- Regulated carcinogen.
- Extremely reactive and unstable compounds.
Other Chemicals that may form peroxides:
Allyl ether d
Allyl ethyl ether
p-(n-amyloxy) benzoyl chloride
Benzyl n-butyl ether d
Benzyl ether d
Benzyl ethvl ether d
Benzyl methyl ether
Benzyl 1 napthyl ether
1,2 Bis (2chloroethoxv)ethane
Bis (2methoxvethoxv)ethyl ether
Bis (2 chloroethyl) ether
Bis (2-methoxvethyl) adipate
Bis (2-ethoxyethyl) phthalate
Bix (2-methoxyethyl) carbonate
Bis (2-methoxyethyl) ether
Bis (2-methoxyethyl) phthalate
Bis (2-methoxymethyl) adipate
Bis (2-butoxyethyl) phthalate
Bis (2-phenoxyethyl) ether
Bis (4-chlorobutyl) ether
Bis (chloromethyl) ether c
3-Bromopropyl phenyl ether
tert-Butyl ethyl ether
tert-Butyl methyl ether
n-Butyl phenyl ether
n-Butyl vinyl ether
Chloroacetadehyde diethylacetal d
Chloromethyl methyl ether c
Diethyl fumarate d
Cyclopropyl methyl ether
Diallyl ether d
1,2 Dichloroethyl ethyl ether
1, 2 Dichloroethyl ethvl ether
Diethyl acetal d
m, o, p – Diethoxybenzene
1,1 Dimethoxymethane d
1,3 Dioxepane d
Di (1 propynyl) ether
Di (2-propynyl) ether
1,2 Epoxy 3-isopropoxypropane d
1,2 Epoxy 3-phenoxpropane
1-(2-Ethoxyethoxy) ethyl acetate
Ethyl Vinyl Ether
2,5 Hexadiyn- 1-ol
4.5 Hexadien-2-yn- 1-ol
Isoamyl benzyl ether d
Isoamyl ether d
Isobutyl vinyl ether
Methyl p-(n-amyloxy) benzoate
3-Methoxy- l-butyl acetate
2-Methoxyethyl vinyl ether
Oxybis (2 ethyl acetate)
Oxybis (2-ethyl benzoate)
Phenoxy acetyl chloride
Phenyl o-propyl ether
Sodium 8, 11, 14 elcosate traenoate
Triethylene glycol diacetate
Trithylene glycol dipropionate
Vinylidene chloride d
Note: There may be more materials that form peroxides.
Use this as a general guide only.
Always refer to the latest research and manufacturers MSDS for current information on the materials you use.